2.27.2007

Emulsion Composition and Role

- " Composition of a classical cosmetic formulation :


Surfactants

Hydrosoluble Polymeres , thickeners

Preservatives

Antibacterians, antiseptic

Humectants and Moisterizers

Pigments

Perfumes

Colorants

Divers additives


photo taken from http://www.lavbeauty.com/skincare.jpg


Aqueous phase :

Composition :

- Sterilised/Deminerilised Water which serves as an excipient.

- Consistency Agents : Those are ploymers able to modify the reological comportment of formulations.

- Chelating Agents : molecule specialised in the capture and the immobilisation of ionic substances coming from cleansing water in order to reduice the risks of oxydation.

- Humectant Agents : added to limit the loss of water in the product.

- pH Regulator : to adjust the pH of the formula (to avoid the fact the product is agressive for the skin).

- Moistening Agents : provoke an immediat and long term effect of skin hydration.


Aqueous phase Functions :

- permits the development of viscosing polymers.

- Takes in actives, preservatives and colorants which are hydrosolubles.

- Restaurates the epidermis hydration by bringing elements able to fix water in the corneous layer of the skin, (elements as water and moisterizing agents).


- Oily phase :

Composition :

- Emollient : it nourishes the skin and play a role in the touchside and texture of the final product.

- Conditioning agents : form a film on the skin or hair to limit agression of surfactants.

- Surfactants : molecules permiting the formulation of the emulsion.

- Perfume phase : containing perfum, antioxydant, preservatives, solubilising.


Oily phase Functions :

- Takes in actives, preservatives, colorants which are liposolubles (soluble in oil).

- Participates to the hydrolipidic film reconstruction favorisating the conservation of the epidermis hydration.

- Gives a particular final touch to the formula.





Source : http://perso.orange.fr/chimie.sup/formulation.htm

2.25.2007

The Surfactants : How does it work ?

Surfactants, have many functions.

That's what we are going to see.


" When used for stabilising an emulsion, surfactants are caracterised with their Hydrophilic - Lipophilic Balance (HLB).



___ 0 _____________________ 18 ___ HLB scale



more lipophilic

more hydrophilic



Surfactant Properties :



The Superficial Tension

Adding a surfactant product dicreases strongly the superficial tension of water with the disposition molecules take inside the liquid.


schema taken from http://images.google.fr/images?hl=fr&q=micelle&ie=UTF-8&oe=UTF-8&um=1&sa=N&tab=wi



It's this disposition which is responsible of the moistening, foaming and emulsioning power.

However reaching a certain concentration in surfactants, called critical micellar concentration (cmc), the surface of the liquid being satured in surfactant molecules, those molecules join theselves together in the liquid forming micelles.












Foaming power :

Surfactants molecules consolidate the thin water layer which forms bubbles.



Cleansing power :

Lipophile parts of surfactants adhere to oily dirt.

The dirt is then captured and carried away inside the micelles, to the washing water.


Emulsifing power


An emulsion is a system constituted by a liquid that is dispersed as thin droplets in an other liquid, both liquid being non miscible.

However, using surfactants, we can have droplets of oil in water or droplets of water into oil.








> A O/W (oil in water) emulsion must have a surfactant with High HLB






schema taken http://images.google.fr/images?q=micelle&ndsp=18&svnum=10&hl=fr&start=54&sa=N



> A W/O (water in oil) emulsion must have a surfactant with low HLB



micelle including a water droplet "






schema taken fromhttp://images.google.fr/images?q=micelle&ndsp=18&svnum=10&hl=fr&start=126&sa=N



> A " human micelle" I found while searching for schemas on the net..nice right? ;-)



photo taken from http://images.google.fr/images?q=micelle&ndsp=18&svnum=10&hl=fr&start=36&sa=N

source : http://www.ac-bordeaux.fr/Etablissement/StLouis/OLYMP/cosmeto/cosmeto.pdf

2.23.2007

The Surfactants : Definition

Definition :

" The surfactants are able to disperse oily main parts in water (cleanser power), to form foam, to stabilise emulsions and to further the interfaces moistening.

Surfactants molecules posess a 6 atoms of carbon chain which is hydrophob ('doesn't like water'), and have a polar group hydrophile (who has affinity with water).
Those molecules having both hydrophob and hydrophile parts are called "amphiphile".
The molecule can be schematised this way :

---------------------O hydrophile part
hydrophob part



Classification :

a) Anionic Surfactant :

----------------(-) the hydrophile part is anionic


Different kind of anionic surfactants :


> derivees of fat acids : RCOO-,Na+ ( R : long chain in C12 to C18 the more often) resulting from saponification of triglycerids (triester of glycerol and fat acid) of vegetal oils.

example : sodium palmitate: CH3-(CH2)14-COO- , Na+

Where do we find them ?

N.B : Soaps containing the sodium ion are tough (we find them in bar of soap), those with potassium ion are smooth (used in shave foams or as surfactants in creams).


> alkylsulfates : R-O- SO3
- R = long chain of carbon : (synthetic detergents )


exemple : ammonium dodecyl sulfate or ammonium lauryl sulfate :
C12H25 – O – SO3- , NH4+

Where do we find them ?

present in toothpaste, shampoos, bath and shower products

b) Cationic Surfactant :

--------------------(+) the hydrophile part is cationic


Kind of Cationic surfactants :

> quaternar ammonium salts : RR1R2R3 N+, allergising and irritating for eyes and skin, are often associed with other kind of surfactnats to attenuate those effects.

They have interesting bactericids properties.

Where do we find them ?

Their conditioning properties make them enter in after-shampoos formulation.

example : cetyltrimethylammonium bromure : C16-H33 N+ (CH3)3 , Br -


c) Non-ionic Surfactant :


The hydrophile part is neutral but strongly polar. Those elements are biologically safe.

> sorbates or esters of sorbitol and fat acids

> sorbitan esters (sorbitan : C6H12O5), and fat acids

Where do we find them ?

in emulsions but also numerous shampoos for their cleanser and foaming power.

d) Amphotere or Zwitterionic Surfactants


They possess two groupments of opposite charge. Following the pH they are under a cationic form or an anionic form.

> derivatives of betaine

> amine acid and their derivative which are often used in cosmetology as co-surfactant (in addition to principal surfactants) to stabilize micro-emulsion.

They are excellent cleanser.

Where do we find them ?

Non irritating, amphoteres enter in the formulation of :

- numerous soft shampoos

- products for sensitive skin

- eye demak up

- dermatological toners and gels "

source : http://www.ac-bordeaux.fr/Etablissement/StLouis/OLYMP/cosmeto/cosmeto.pdf and translated by me

What is an Emulsion ?

Emulsion :

Liquid droplets dispersed in another immiscible liquid.

The dispersed phase droplet size ranges from 0.1 - 10 µ m.

Let's talk about what every one knows more : food.
Important oil-in-water food emulsions, ones in which oil or fat is the dispersed phase and water is the continuous phase, include milk, cream, ice cream, salad dressings, cake batters, flavour emulsions, meat emulsions, and cream liquers.

Examples of food water-in-oil emulsions are butter or margarine.

Actually in cosmetics, the system is the same, imagine the margarine is a facial cream. The same way you got the margarine, you get your cream by introducing a phase containing water
and other elements in an oily phase.
The unique difference between the food products and cosmetics are in raw materials used.
Even though some raw materials used in food can also be used in cosmetics, I will take an example : Argan oil you can consum but used in cosmetics, rich in vitamins E it prevents skin against aging, because anti oxydant. It is also advised for very dried skin. It also has a restruturing role. Of course, being a unique oil coming from Morocco, its price is expensive and not used in big quantity. However, it can be used as an active.

Emulsions are unstable and thus do not form spontaneously.


Energy input through shaking, stirring, homogenizers, or spray processes are needed to form an emulsion. Over time, emulsions tend to revert to the stable state of oil separated from water.

Surface active substances (surfactants) can increase the kinetic stability of emulsions greatly so that, once formed, the emulsion does not change significantly over years of storage.

Homemade oil and vinegar salad dressing is an example of an unstable emulsion that will quickly separate unless shaken continuously. This phenomenon is called coalescence, and happens when small droplets recombine to form bigger ones.

Fluid emulsions can also suffer from creaming, the migration of one of the substances to the top of the emulsion under the influence of buoyancy or centripetal force when a centrifuge is used

Emulsions are part of a more general class of two-phase systems of matter called colloids. Although the terms colloid and emulsion are sometimes used interchangeably, emulsion tends to imply that both the dispersed and the continuous phase are liquid.


There are three types of emulsion instability: flocculation, where the particles form clumps; creaming, where the particles concentrate towards the surface of the mixture while staying separated; and breaking, where the particles coalesce and form a layer of liquid




To recapitulate, by adding well chosen surfactants you can realise an emulsion by "mixing" a water phase and a oily phase all together, thing that is normally impossible :D (imagine a water drop added to your tournesol oil..they don't mix)

Actually the two phases are not mixed in reality, but from a human eye the two phases seem "mixed". They are maintened by the surfactants.


A little practical schema :


A : an oily phase B is added to a a water phase A.
Two immisicible liquids, not emulsified

B : With shaking strongly you can have an emulsion of phase B dispersed in phase A.


C : But because the emulsion is unstable, the two phases tend to separate from each other since the tension between the two interfaces is too strong.


D : By adding surfactants, the surfactants (purple outline) position themselves on the interfaces between the two phases, stabilizing the emulsion.

source : http://en.wikipedia.org/wiki/Emulsion


I will talk about those impressive surfactants in the next chapter. By their structure, you will understand their properties detailed above.


For those who discover formulation, I tried not to make it sound too complicated, anyway if you have questions, feel free to ask :-)

The South Korean Cosmetic Market

With sales estimated to 4,3 billion euros in 2005, South Korea is the 3rd Asian market concerning cosmetics. This market is caracterised by a very consumer clientele (approximatively 230 euros per customer in 2006), and a clientele not devotee to one mark in particular. Successful products in South Korea are essentially facial skincare products, make up, manucure, pedicure (nails products) but also men products strongly progressing.






I like this actress Kim Tae Hee.



http://image.blog.livedoor.jp/koreanstyle/imgs/e/8/e8da79a0.jpg



Korea has for a long time being described as the "Eldorado" for imported cosmetic products. It is true that korean people are fond of famous occidental marks. However, they become more and more difficult to satisfy : a simple "Made in France" is not enough anymore to sell in Korea.




Now you have to take local style and liking in consideration, exploit different kind of advertisement to promote your cosmetics and offer better quality products.
Especially when local manufacturers resist to occidental suppliers even in luxurious brand.




The local production represents 2/3 of the actual market and it is not rare observing in Corner Shops of big supermarket, korean products themselves.



Korean Legislation can seem restrictive concerning the input of imported products on the korean Market. Solar products, whitening products and Anti age products have stricter conditions and legislation being considered as more "penetrating" in the skin (filters, anti age actives).

source : http://www.missioneco.org/Coree/documents_new.asp?V=7_PDF_123302 and translated by me






A wonderful actress and model too : Song Hye Kyo.

http://rpm_737.blogs.friendster.com/photos/song_hyekyo/cover-image-song%20hye%20kyo%20cover%20image.jpg



2.22.2007

The cosmetic market in the World


Occidental Europe, with its important population of 388 millions resident is the biggest market in the world with 31,5 billion euros , in 2000.


Switzerland is in first position at both european and world-wide scales, concerning consommation of cosmetics per resident, followed by Japan, United States and France.


Source : http://www.fnege.net/pdf/04partie3/Z-2004.pdf and translated by me


While in Europe, women use 5 to 6 cosmetic products per day, Asia is the sector where the consomation is the largest : Japanese women use between 16 to 18 creams and toners per day and the best consumer is the Korean woman with at least 20 dayly product application !

taken from http://images4.dantri.com.vn/Uploaded/vannt/jeon300906.jpg

For this reason, many european industries export cosmetics in Asia and implant local industries in key towns like Tokyo, Shangai and Seoul.

France is the 3rd supplier of cosmetics in Asia with 13% market share in China.



With a beauty criteria claiming for a white skin in Asia, this continent is the first market in the whole world for suncare products used for protecting skin against UVs.

Of course Asia has its own local cosmetic manufacturer and even tend to concurrence the biggest companies of the world, trying to expend themselves in Asian key countries.


Because I have a big and special interest for Korea, and also because many people don't know much about this interesting and dynamic coutry, I will introduce the korean market in more details in the following chapter.


taken from http://images.google.fr/images Song-hye-Kyo


2.21.2007

The Skin : Introduction

The skin is the body's largest organ (2m2 for 5 kgs at the adult age!!). It has many important roles such as regulating body temperature, maintaining water and sensing all kind of stimuli.
Thanks to his chemicals, the skin represents a barrier against dangerous substances from entering the body and is the first protection again the harmful effects of ultraviolet radiation emitted by the sun.

Plus texture and skin color make us all diferent as individuals : see this photo of twins.


photo taken from http://www.msnbc.msn.com and translated by me.

One was born black, the other one white, of course for a genetic reason, rare though (one in a million case), but in the end although twins are known for their ressemblance, those beautiful babies by their skin appearence look different :-) Interesting case isn't it?


2.20.2007

My Job in a different company

Well, after the training period I realised in a big cosmetic group in Paris, waiting for my first job as a cosmetic formulator I worked first as a chemist technician where I had to measure viscosity and elasticity of polymers used in painting for drinking bottles (but also all the painting used on biscuit boxes..).

This was job was not directly in the field I graduated from, it was still very interesting because in cosmetics too, those kind of analysis are used to determine or understand the comportement of fluids or solids. As a technician you should enlarge your knowledge about methods of analysis because a product for the consumer has to be safe, and to be sure it is, I guess you imagine tests are made (at least to be sure of the stability of the product).

Actually the job was based at the University I graduated from, and I was managed by the Professor in charge with the branche I graduated from : "La licence professionnelle formulation cosmétique" (The Professional Bachelor 'Cosmetic Formulation'), Mr Michel Grisel.
Through this little message I want to thank again Mr Grisel for his kindness and everything I learned during the formation but also during my job as an analytical technician.
Mr Grisel has majored in Rheology and was a teacher at the University of Le Havre until he became Professor last year!! And he is only in his early 30's! Congrat' by the way
Ah, and he was the one in charge with the "Licence Professionnelle Formulation Cosmétique" I attended to.

So, after this very first experience interesting and with a very friendly atmosphere I found my very first job as a cosmetic technician formulator in mid june 2006. I was expected to finish work in the University until late july but thanks to Mr Michel Grisel, I have been able to begin work in Paris in june, so I am grateful and thankful to him. (Merci!! hé hé)

I was very excited about my next future experience! It was just like something you are so much expecting that in the end you're not totally sure if you are excited or stressed up!!

But I guess I was very stressed upon the fact I had no way to resid in Paris yet! Finding a studio or an apartment is not an easy matter..especially when you have to start work one week later!! So actually for the two first weeks, I had to go to work by train ( seriously I was exhausted but you always have to remember others might be living twice harder the pain you feel somewhere else... so I usually just try to never complain anyhow.

Fortunately, my father knows someone in Paris who had a studio, so he asked him if I could be the next lodger... So here was the beginning of my new life in Paris!

Let's go back to my first day of work. I first met with my boss, in charge with the laboratory of formulation. She is in her late 20's and was very worried about the good fonctionement of the laboratory.
Céline explained me a lot about the system and what my role was and I was quickly enrolled in my position.
The laboratory in itself is small and has its own account, but it belongs to a big group actually.

Contrary to my training period, I had to work more with people around and especially the Marketing Service. Their work is to contact customers in order to propose them a range of interesting products which will lead to a contract between the two sides. Of course, this is not their only task, but the most important one in the beginning. And this step will lead the laboratory to work and formulate products in order to present them in their packages, to the customers, who will then decide if the products respond to their quality and price criteria.

So, as you understood, if customers don't like the products or if the prices are too high, then you lose and you can forget about the contract. Of course this is a "way of work" and it is not the only one. For this company I worked for, this way of work is the most frequently seen.

But in other case, the company doesn't have to "win" a customer. Some customers the company already is engaged with will ask for some products and detail their needs. So we all work closely and with the same goal : making great products the customer will be proud of.

So of course the tense is different when you have to "win" the customer (not the customer who buys the products in a shop but a potential customer whose role is having cosmetic products to sell in their supermarket or in luxurious shops ^^), because you have competitors.
And having competitors means having maybe better prices propositions from the adversal side !

So the slogan is : "Better products with better prices and greatest quality!"

It was very interesting in the way you are always making all the best to take all those points in consideration. Although it was not easy, a beginner has to remember experimented people are around and you have to consult them when you feel like you don't have the answer, especially if the non-question-asked will lead to sad consequences. So when you feel like you don't have the answer or can not find it by yourself try and consult people around you, although you feel they are not really "hot" about it. That's the best way to learn, if of course tons of questions are not asked in a same day!! lol

Ok, so for my first task, I was asked to formulate a wide range of products (11 products). They were cleaning products like toners, eyes demak up.. and skincare products for facial and body.
A lot of things to learn and a lot of tasks to deal with.
The whole work had to be done in three weeks, containing research about formulas, prices, formulation process and stockage or package of products which will be finally taken away by the Marketing service who will then go and present them to the Customer.

At first I felt like a tone of pressure because everything went just so fast and lots of things and computer datas and logiciels had to be memorized as daily encountered.
Also, this company can not afford "errors" since this was not a big structure in itself, so you have to keep in mind that saving money in all you do is very important. The hardest maybe is that you have to save money on formulas so choosing the cheapest raw materials without neglecting the good quality is a crucial task. Of course, then, saving money in all you spare and you could have spared is a comportement you should adapt anywhere else you work.. isn't it ;-)
But just like anybody you just have to take the stress away and make the most of your competences and time.

Finally, everything went fine, well not without pain but it worthed it. When you see all the work and effort you made in those, and you see the result, you are relieved and glad too ;-)

Of course there were different things asked during those months I spent in this company, and I had the opportunity to deal with shampoos, shower gels, handcream, serum for hair, suncare products, plus the skincare products and cleaning ones I described above.


So it was a great experience, and I guess I was very lucky to start dealing with all the tasks required for accomplishing my work. I also worked with different services, just like the ones I described in the chapter "My training period experience".


Note : Special thanks to Michel and Céline for their trust in me and all the things I have been able to do with their help and smile :-) Merci encore.

2.16.2007

My training period experience

In this message I will try to explain what my jobs consists in.
First of all, a cosmetic formulator technician doesn't do just one thing but has to be "multiplayer". He does not only work in laboratory but with other services.

All cosmetic formulators don't do exactely the same job, it will depend on which departement you are and of course, it depends of the kind of cosmetic product you create or developp.


Developping and renovating is here a bit different.

If the company wants you to extend a new range of product, then you will do some developpement. You could think about the raw materials to put in the formula and first make sure the product is stable. You will have a previous work to do by searching for suppliers formulas or take inspiration by what already exists inside the company.

If the company wants you to renovate a product, then it means you have to take the formula as it is but bring amelioration to it, be it on smell (so a modification of perfume or add or retrieve eventual essential oils), or on touch (here you can bring a lot of solutions, depends on the case).

No matter what your job consists in, all technician formulators have to be sure the products are stable and safe for the customer' s sake.


A little bit about my experiences :

I was graduated in September 2005 and I have a Bachelor's degree (3years after highscool diploma). In France, you have lots of formation just like the one I did. It can allow you working younger and do technical works, just like a cosmetic or chemist formulator who will work both in laboratory and in an "office". Generally, offices are in a room next the laboratory but can also be disposed inside the laboratory.

Generally, you'd need a computer to search for technical datas, work on excel and create your formulas, consult your work mailbox.

You'd also need a phone because most of the time you will work with different services just like the Marketing service, external suppliers, people from factories who work on bigger scale than you in your laboratory, people specialized in biology and perfume, or flower extratcs.. Analytical Service and people in charge with the legislation, specialists who will make a validation of your formula ... So when you work alone in your laboratory, actually you have to be open minded and remember that people besides work also on your project, with different tasks on it but you have to consult people around you before and during the formulation to be sure not only your product (i mean the formula, the aspect or smell) is right but the legislation too is respected.

By formulation I mean the "formation or elaboration" of the product. By using different cosmetic raw materials, like cosmetic oils, polymers, chelating agents etc..by using different methods as emulsions (introduction of a water phase in an oily phase containing tensioactifs which will permit the homogeneous mixture between the two elements (the introduction can be on the other sens, depending of what kind of texture you are searching for : oily or not)



So, the last year I made in University was a professional field. It means that along the year, you don't have only theorical courses but lots of pratical courses too, where you learn the meaning and the effect of different raw materials. You have to formulate different products, from shampoos to skincare products, passing by some make up products like complexion or lipstick.

We did not formulate a lot of make up products but more white products (skin care) and hygiene products : shampoos, shower gels and hair products (fixing gel).

So when people hear "Cosmetic" they often understand it as being make up only, but as the definition says all above, a cosmetic product is every product you put on you superficial body parts with the only purpose of cleaning you, making you feel fresh and all.


During this year of College, I realized my training course in a cosmetic company in Paris I won't nominate for confidentiality. I will just explain what my job consisted in.

It was in the Suncare research Department.

I had to test a new raw material in a new support which was not stable while containing a certain dose of this raw material. So first I had to find the right dose to introduce before thinking of ameliorating the formula (amelioration of the aspect, the smell, and the touch side).

So I had the opportunity to in the same time, doing some preresearch on the formula and some "development" since I had to find different raw materials to make the formulas "go better" while remaining stable.
The stability was evaluated 2months at 5O°C in a kind of even for products.

What is very important when you formulate a suncare product is that this product has to be efficient and must protect the skin and be water resistant. So you also have to test your products in vitro (not on the skin but with an apareillus first to know approximatively the amount you reach concerning the SPF mesure (Solar Protection Factor). I was able to take the mesures since we had the material inside the laboratory.
Of course in the end you have to test it in vivo, so on human (a test realised in an other service with specialists of course)

While formulating a solar product, you have to be vigilent to the filters you use (for instance, you must not heat them too much depending on the nature of the filters (sometimes you can have a bad surprise of colour due to this phenomenon) ).
During my training course, as I said previously, I had to formulate new fluid O/W (oil in water) suncare products. Fortunately, I have been able to obtain 4 stable and efficient formulas we have been able to present to the Developement departement.

Actually, the Research departement's role is to test new raw material in different support of formula, in order to improve (in a long term vision) what is already on the market or make sure in the future developement process, new technical methods or new elements will be used in order to impress the customers and be on top in the cosmetic market.
My training period was realised in a very big structure, so you can just imagine the money spent on the research and new raw materials, approach and numerous contacts with different suppliers of new raw materials.
But you will see that my point of view about my work can be interesting as for my other job I worked in a smaller structure where everything had to be counted.
So after my presentation of all the work realised and the results obtained in the Developement Department, they were particularly interested in one of the formulas which was interesting for its softness and efficiency, but it was also the cheapest! So yes, of course the price of the formula per kilogram is really important too. It permits to know how much you are going to spend per year and what marge you must do for gaining benefits from it..:-)
When you work in a smallest company, Quality is very important of course but it must come with the money matter. So both experiences in both companies were extremely interesting and I learned a lot from it, and from my seniors too.

In that case this is much more difficult but also so much interesting !
I only talked about my professional experience, but I think I should talk about people and how I felt there. I was directly managed by a technician (which is also my status) in the same laboratory I was. He was a bit more than 10 years older than me and really knows his job. I always respected him. He is now a very good friend of mine :-) Not the kind of friends who see each other very often, but when I returned to Paris for my first job as a cosmetic formulator, although I wasn't able to see him much, I took a café with him and he just told me everything he lived from the moment I finished working with him :-) (Merci K.B !!)

So as much as being precise when you weigh the raw materials you need, being very attentive during the formulation is also part of our job.


Note to my readers : If you need more details about what kind of methods you have to formulate each or each product, don't hesitate to ask (i'll try my best to answer you), just know that make up is not my speciality ^^ well not yet since I only really worked on skin and suncare products, hygiene, hair products. I will write more about my experience later, maybe tonight again ;-)
Don't hesitate to post comments. If some things appear wrong to you, just know I am writing my personal experience, maybe other people will feel it differently, but don't hesitate to say or ask anything you are curious about!





Cosmetic Products : Definition


A cosmetic product is a product made to be in contact with superficial body parts, such as the epiderm, hair, nails, lips, teeth.. in order to clean those parts, perfume them, protect them, keep them in good state and correct our corporal odour.

So when you create a cosmetic product you don't create a pharmaceutical product which will penetrate deeply in your skin and cure you for instance. Those two products have different roles and should not be considered as being the same element.

Rules and legislation in Cosmetic formulation exist to keep this difference alive and real.